Solution Concentration Page:
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2. normality (N) = equivalents of solute / dm3 solution
Normality is a useful concentration unit to use during neutralization reactions (titrations). One mole of hydrogen ions reacts with one mole of hydroxide ions to produce water. But that doesn't mean that one mole of any acid will neutralize one mole of any base. Chemists need a unit for the amount of acid (or base) that will give one mole of hydrogen (or hydroxide) ions.
One equivalent is the amount of an acid (or base) that will give one mole of hydrogen (or hydroxide) ions.
The numerical values of normality and molarity are equal for acids and bases that give 1 equivalent of H+ or OH − per mole.
Examples:
- What is the Normality of a 1M solution of NaOH?
- N = molarity X # OH− in the formula.
- N = 1 X 1 = 1N
- What is the Molarity and the Normality of a solution containing 1 mole of H2SO4 / dm3 ?
- M = moles/dm3 = 1M
- N = M X # H+ in the formula = 1 X 2 = 2N
- 1M H2SO4 is 2N because it contains 2 equivalents of H+ per mole.
- What is the Normality of a 2M solution of aluminum hydroxide?
- Al(OH)3 has 3 hydroxide ions in its formula.
- N = molarity X # OH− = 2 X 3 = 6N
- Each mole of Al(OH)3 contains 3 equivalents of OH−. Since we have 2 moles, we have 6 equivalents, or 6N.
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