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MSDS for AMMONIUM HYDROXIDE Page 1

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1 - PRODUCT IDENTIFICATION

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PRODUCT NAME: AMMONIUM HYDROXIDE

FORMULA: NH4OH

FORMULA WT: 35.05

CAS NO.: 01336-21-6

NIOSH/RTECS NO.: BQ9625000

COMMON SYNONYMS: AMMONIA SOLUTION; AQUA AMMONIA

PRODUCT CODES: 4807,9730,9733,5350,9719,9729,5358,9721,9731,5019,9720,5138

EFFECTIVE: 09/03/86

REVISION #02

 

PRECAUTIONARY LABELLING

BAKER SAF-T-DATA(TM) SYSTEM

 

HEALTH - 3 SEVERE (POISON)

FLAMMABILITY - 1 SLIGHT

REACTIVITY - 2 MODERATE

CONTACT - 3 SEVERE (CORROSIVE)

HAZARD RATINGS ARE 0 TO 4 (0 = NO HAZARD; 4 = EXTREME HAZARD).

 

LABORATORY PROTECTIVE EQUIPMENT

 

GOGGLES & SHIELD; LAB COAT & APRON; VENT HOOD; PROPER GLOVES

 

PRECAUTIONARY LABEL STATEMENTS

 

POISON DANGER

CAUSES BURNS

MAY BE FATAL IF SWALLOWED

VAPOR EXTREMELY IRRITATING

EXCEPTIONAL HEALTH AND CONTACT HAZARDS - READ MATERIAL SAFETY DATA SHEET

DO NOT GET IN EYES, ON SKIN, ON CLOTHING.

AVOID BREATHING VAPOR. KEEP IN TIGHTLY CLOSED CONTAINER. LOOSEN CLOSURE

CAUTIOUSLY. USE WITH ADEQUATE VENTILATION. WASH THOROUGHLY AFTER

HANDLING. IN CASE OF SPILL, FLUSH SPILL AREA WITH WATER.

 

SAF-T-DATA(TM) STORAGE COLOR CODE: WHITE STRIPE (STORE SEPARATELY)

 

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2 - HAZARDOUS COMPONENTS

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COMPONENT % CAS NO.

 

AMMONIUM HYDROXIDE 20-30 1336-21-6

 

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3 - PHYSICAL DATA

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BOILING POINT: N/A VAPOR PRESSURE(MM HG): N/A

 

 

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MSDS for AMMONIUM HYDROXIDE Page 2

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MELTING POINT: -78 C ( -108 F) VAPOR DENSITY(AIR=1): N/A

 

 

SPECIFIC GRAVITY: 0.90 EVAPORATION RATE: N/A

(H2O=1) (BUTYL ACETATE=1)

 

SOLUBILITY(H2O): COMPLETE (IN ALL PROPORTIONS) % VOLATILES BY VOLUME: 100

 

APPEARANCE & ODOR: CLEAR COLORLESS SOLUTION WITH A STRONG ODOR.

 

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4 - FIRE AND EXPLOSION HAZARD DATA

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FLASH POINT (CLOSED CUP: N/A NFPA 704M RATING: 3-1-0

 

FLAMMABLE LIMITS: UPPER - N/A % LOWER - N/A %

 

FIRE EXTINGUISHING MEDIA

USE EXTINGUISHING MEDIA APPROPRIATE FOR SURROUNDING FIRE.

 

SPECIAL FIRE-FIGHTING PROCEDURES

FIREFIGHTERS SHOULD WEAR PROPER PROTECTIVE EQUIPMENT AND SELF-CONTAINED

BREATHING APPARATUS WITH FULL FACEPIECE OPERATED IN POSITIVE PRESSURE MODE.

MOVE EXPOSED CONTAINERS FROM FIRE AREA IF IT CAN BE DONE WITHOUT RISK.

USE WATER TO KEEP FIRE-EXPOSED CONTAINERS COOL; DO NOT GET WATER INSIDE

CONTAINERS.

 

UNUSUAL FIRE & EXPLOSION HAZARDS

GIVES OFF FLAMMABLE VAPORS. VAPORS MAY FORM EXPLOSIVE MIXTURE WITH AIR.

CLOSED CONTAINERS EXPOSED TO HEAT MAY EXPLODE.

 

TOXIC GASES PRODUCED

AMMONIA, HYDROGEN GAS

 

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5 - HEALTH HAZARD DATA

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TOXICITY TEST RESULTS AND SAFETY AND HEALTH EFFECTS ARE BASED ON

THE SOLUTE.

 

THRESHOLD LIMIT VALUE (TLV/TWA): 18 MG/M3 ( 25 PPM)

 

SHORT-TERM EXPOSURE LIMIT (STEL): 27 MG/M3 ( 35 PPM)

 

PERMISSIBLE EXPOSURE LIMIT (PEL): 35 MG/M3 ( 50 PPM)

 

TOXICITY: LD50 (ORAL-RAT)(MG/KG) - 350

 

CARCINOGENICITY: NTP: NO IARC: NO Z LIST: NO OSHA REG: NO

 

EFFECTS OF OVEREXPOSURE

INHALATION OF VAPORS MAY CAUSE SEVERE IRRITATION OR BURNS OF THE

RESPIRATORY SYSTEM, PULMONARY EDEMA, OR LUNG INFLAMMATION.

CONTACT WITH SKIN OR EYES MAY CAUSE SEVERE IRRITATION OR BURNS.

PROLONGED EYE CONTACT MAY CAUSE PERMANENT DAMAGE TO THE CORNEA AND

 

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MSDS for AMMONIUM HYDROXIDE Page 3

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BLINDNESS MAY OCCUR.

INGESTION MAY CAUSE SEVERE BURNING OF MOUTH AND STOMACH.

INGESTION IS HARMFUL AND MAY BE FATAL.

 

TARGET ORGANS

RESPIRATORY SYSTEM, EYES

 

MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE

NONE IDENTIFIED

 

ROUTES OF ENTRY

INHALATION, INGESTION, EYE CONTACT, SKIN CONTACT

 

EMERGENCY AND FIRST AID PROCEDURES

CALL A PHYSICIAN.

IF SWALLOWED, DO NOT INDUCE VOMITING; IF CONSCIOUS, GIVE LARGE AMOUNTS OF

WATER. FOLLOW WITH DILUTED VINEGAR, FRUIT JUICE OR WHITES OF EGGS, BEATEN

WITH WATER.

IF INHALED, REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL

RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN.

IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES OR SKIN WITH PLENTY OF WATER FOR

AT LEAST 15 MINUTES WHILE REMOVING CONTAMINATED CLOTHING AND SHOES.

WASH CLOTHING BEFORE RE-USE.

 

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6 - REACTIVITY DATA

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STABILITY: STABLE HAZARDOUS POLYMERIZATION: WILL NOT OCCUR

 

CONDITIONS TO AVOID: HEAT

 

INCOMPATIBLES: STRONG ACIDS, ALKALI METALS, STRONG OXIDIZING AGENTS,

BROMINE, CHLORINE, ALUMINUM, COPPER, BRASS, BRONZE,

MERCURY, DIMETHYL SULFATE

 

DECOMPOSITION PRODUCTS: AMMONIA

 

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7 - SPILL AND DISPOSAL PROCEDURES

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STEPS TO BE TAKEN IN THE EVENT OF A SPILL OR DISCHARGE

WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING. STOP

LEAK IF YOU CAN DO SO WITHOUT RISK. VENTILATE AREA. CAREFULLY NEUTRALIZE

SPILL WITH DILUTE HCL. FLUSH AREA WITH FLOODING AMOUNTS OF WATER. (USE

CAUTION.)

 

J. T. BAKER NEUTRACIT-2(R) CAUSTIC NEUTRALIZER IS RECOMMENDED

FOR SPILLS OF THIS PRODUCT.

 

DISPOSAL PROCEDURE

DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE, AND LOCAL

ENVIRONMENTAL REGULATIONS.

 

EPA HAZARDOUS WASTE NUMBER: D002, D003 (CORROSIVE, REACTIVE WASTE)

 

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8 - PROTECTIVE EQUIPMENT

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MSDS for AMMONIUM HYDROXIDE Page 4

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VENTILATION: USE GENERAL OR LOCAL EXHAUST VENTILATION TO MEET

TLV REQUIREMENTS.

 

RESPIRATORY PROTECTION: RESPIRATORY PROTECTION REQUIRED IF AIRBORNE

CONCENTRATION EXCEEDS TLV. AT CONCENTRATIONS

UP TO 25 PPM, A CHEMICAL CARTRIDGE RESPIRATOR

WITH AMMONIA/AMINE CARTRIDGE AND DUST/MIST FILTER

IS RECOMMENDED. ABOVE THIS LEVEL, A SELF-

CONTAINED BREATHING APPARATUS IS ADVISED.

 

EYE/SKIN PROTECTION: SAFETY GOGGLES AND FACE SHIELD, UNIFORM,

PROTECTIVE SUIT, RUBBER GLOVES ARE RECOMMENDED.

 

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9 - STORAGE AND HANDLING PRECAUTIONS

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SAF-T-DATA(TM) STORAGE COLOR CODE: WHITE STRIPE (STORE SEPARATELY)

 

SPECIAL PRECAUTIONS

KEEP CONTAINER TIGHTLY CLOSED. STORE IN CORROSION-PROOF AREA.

STORE BELOW 25 C.

 

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10 - TRANSPORTATION DATA AND ADDITIONAL INFORMATION

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DOMESTIC (D.O.T.)

 

PROPER SHIPPING NAME AMMONIUM HYDROXIDE (12-44% AMMONIA)

HAZARD CLASS CORROSIVE MATERIAL (LIQUID)

UN/NA NA2672

LABELS CORROSIVE

REPORTABLE QUANTITY 1000 LBS.

 

INTERNATIONAL (I.M.O.)

 

PROPER SHIPPING NAME AMMONIA SOLUTIONS (10-35% AMMONIA)

HAZARD CLASS 8

UN/NA UN2672

LABELS CORROSIVE